Conventional phosphor-converted light-emitting diodes (LEDs) using silicone binders often suffer from yellowing, moisture degradation, and limited spectral tunability, restricting their performance in high-power street lighting. To overcome these limitations, this study aims to develop an advanced LED illumination system integrating a KBr-doped sol-gel/silica phosphor with total internal reflection (TIR) lenses and a reflective housing, encapsulated by an atomic layer deposition (ALD)-coated minilens panel. The sol-gel matrix, synthesized from MTEOS, TEOS, and silica granules, was engineered to achieve uniform KBr particle dispersion, reduced thermal quenching, and improved chromatic stability. The ALD laminate provides an additional moisture and heat barrier, sealing micro-defects and minimizing stress-induced cracking. Optical performance was quantitatively assessed using Monte Carlo beam-tracking simulations under various street configurations, including focal, zigzag, and single-plane pole layouts. Results demonstrated enhanced luminous efficacy, precise glare control, and high uniformity in street illumination. Overall, this integrated sol-gel/ALD LED design effectively addresses the durability and color instability problems of traditional silicone systems, offering a scalable and energy efficient solution for next-generation street lighting.